Self-assembly of single walled carbon nanotubes onto cotton to make conductive yarn_中国颗粒学会

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Partic. vol. 10 no. 4 pp. 517-521 (August 2012)
doi: 10.1016/j.partic.2011.06.011

Short communication

Self-assembly of single walled carbon nanotubes onto cotton to make conductive yarn

Wei Zhanga, b, *, Yee Yuan Tana, Chengwei Wuc, S. Ravi P. Silvaa

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wei.zhang@dlut.edu.cn

Highlights

    ► Poly(ethylene imine) treated cotton yarn is immersed in the single walled carbon nanotube (SWCNT) dispersion in Acid Red 91 solution to make SWCNTs self-assembled onto the yarn. ► The SWCNT functionalized yarn exhibits electrically conductive behaviour. ► The obtained yarn is used to make chemiresistor for detecting ammonia gas.

Abstract

A simple, economical and scalable technique is demonstrated to make conductive yarn. Single walled carbon nanotubes (SWCNTs) are non-covalently functionalized with dye (Acid Red 91) and dispersed in water; while cotton yarn is treated with poly (ethylene imine). When the resulting yarn is immersed in the SWCNT dispersion, SWCNTs self-assemble onto the yarn due to electrostatic forces between the functionalized nanotubes and yarn. Scanning electron microscopy, transmission electron microscopy and Raman spectroscopy indicate the assembly of carbon nanotubes. The SWCNT functionalized yarn exhibits reasonable electrical conduction behaviour and are then used to make chemiresistors. The electrical resistance of the chemiresistors used as sensors increases on exposure to ammonia gas, which can be explained in terms of electron transfer between gas molecules and SWCNTs.

Graphical abstract

Schematic illustration of the experimental principle.


Keywords

Carbon nanotubes; Electrical conduction; Sensor; Ammonia